Molecular structure in correlation with electrochemical properties of mixed-ligand cobalt(III) complexes
نویسندگان
چکیده
منابع مشابه
Spectral, Electrochemical and Molecular Orbital Studies on a New Solvatochromic Binuclear Mixed Ligand Copper(II) Complexes
A new series of solvatochromic binuclear mixed ligand complexes with the general formula: Cu2(DMCHD)(Am)2X3 (where, DMCHD: 5.5-Dimethyl cyclohexanate 1,3-dione, Am=N,N,N’-trimethylethylenediamine (Me3en), N,N,N’,N’tetramethylethylenediamine (Me4en), or N,N,N’,N’,N’’-penta-methyldiethylenetriamine (Me5dien) and X=ClO4or Clhave been synthesized and characterized by the analytical, spectral method...
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هدف از این مطالعه طراحی یک روش کلی برای سنتز یک سری از کمپلکس های دو هسته ای متقارن سیکلومتاله شده پلاتین (ii) بوده که دارای یک لیگاند پل زن(1,2-bis[bis(pentafluoro-phenyl)phosphino]ethane),dfppe, است. از واکنش cis-[pt(r)2(sme2)2]، که در آنr= para-tolyl ، با یک اکی والان از لیگاند benzo[h]quinoline,bhq، در استون محصول [pt(r)(bhq)(sme2)] که در آن r= para-tolyl بدست می آید. همچنین از واکنش 5/0 اک...
Synthesis and Studies of Spectral and Thermal Properties of Some Mixed Ligand Complexes of Thorium(IV) and Dioxouranium(VI) With Semicarbazones as Primary Ligand and Sulfoxide as Secondary Ligand
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The mixed potential response for NO and NO2 from two different oxide electrodes on yttria-stabilized zirconia (YSZ) was examined at 500 jC. The two electrodes were La0.6Sr0.4Fe0.8Co0.2O3 (LSFCO) and Cr2O3. Sensors made with LSFCO electrodes had consistently lower sensitivity towards NOx as compared to those with Cr2O3 and the focus of this paper is to understand the fundamental reasons for the ...
متن کاملThe Analytical Chemistry of Mixed Ligand Complexes
Mixed ligand complexes are characterized by their extreme stability. The chemical individuality of the central atom displays itself clearly, and peculiarities in extractions with organic solvents may be observed. Such properties open new routes to the solution of various theoretical and practical problems in analytical chemistry; true mechanisms and kinetics of analytical reactions can be eluci...
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ژورنال
عنوان ژورنال: Journal of the Serbian Chemical Society
سال: 2008
ISSN: 0352-5139,1820-7421
DOI: 10.2298/jsc0807761b